Chelsea's return to the Champions League ended in disappointment as Ross Barkley missed a late penalty that ensured Valencia claimed victory at Stamford Bridge.
Frank Lampard's first game as a manager in the tournament he won as a player with Chelsea in 2012 turned into a night of frustration as Valencia took advantage of slack marking at a free-kick for Rodrigo to score the winner on 74 minutes.
Chelsea, who lost in-form youngster Mason Mount to injury early on, had the chance to rescue a point when referee Cuneyt Cakir awarded a penalty for handball after consulting VAR when Daniel Wass blocked Fikayo Tomori's header.
Barkley had only come on as a substitute eight minutes earlier but insisted taking the spot-kick instead of the Blues' regular taker Jorginho and Willian, who argued his own case to take it before relenting.
It was a tight and tense encounter with chances at a premium and a tricky Group H, which also includes Lille and last year's semi-finalists Ajax, has got even tougher for Chelsea after starting their campaign with a damaging home loss.
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